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Table of Contents
Introduction
About This Book
Conventions Used in This Book
What You Don’t Need to Read
Foolish Assumptions
How This Book Is Organized
Part I: Reviewing Some General Chemistry
Part II: Rules of Attraction: Chemical Bonding
Part III: It’s Elemental: Dining at the Periodic Table
Part IV: Special Topics
Part V: The Part of Tens
Icons Used in This Book
Where to Go from Here
Part I: Reviewing Some General Chemistry
Chapter 1: Introducing Inorganic Chemistry
Building the Foundation
Losing your electrons
Splitting atoms: Nuclear chemistry
Changing pH
Getting a Grip on Chemical Bonding
Traveling Across the Periodic Table
Hyping up hydrogen
Moving through the main groups
Transitioning from one side of the table to another
Uncovering lanthanides and actinides
Diving Deeper: Special Topics
Bonding with carbon: Organometallics
Speeding things up: Catalysts
Inside and out: Bio-inorganic and environmental chemistry
Solid-state chemistry
Nanotechnology
Listing 40 More
Chapter 2: Following the Leader: Atomic Structure and Periodic Trends
Up an’ Atom: Reviewing Atomic Terminology
Sizing up subatomic particles
Knowing the nucleus
Going orbital
Distinguishing atomic number and mass number
Identifying isotopes
Grouping Elements in the Periodic Table
Keeping up with periodic trends
Measuring atomic size
Rating the atomic radius
Eyeing ionization energy
Examining electron affinities
Noting electronegativity
Chapter 3: The United States of Oxidation
Entering the Oxidation-Reduction Zone
Following oxidation state rules
Scouting reduction potentials
Walking through a Redox Reaction
Isolating Elements
Mechanically separating elements
Using thermal decomposition
Displacing one element with another
Heating things up: High-temperature chemical reactions
Relying on electrolytic reduction
Chapter 4: Gone Fission: Nuclear Chemistry
Noting Nuclear Properties
Using the force
The empirical strikes back
Documenting Atomic Decay: Radioactivity
Alpha radiation
Beta radiation
Gamma radiation
The half-life principle
Blind (radiocarbon) dating
Radioisotopes
Catalyzing a Nuclear Reaction
Fission
Fusion
Chapter 5: The ABCs: Acid-Base Chemistry
Starting with the Basics: Acids and Bases
Developing the pH Scale
Calculating pH
Calculating acid dissociation
Touring Key Theories: A Historical Perspective
The early years
Brønsted-Lowry theory
Accepting or donating: Lewis’s theory
Comparing Lewis and Brønsted theories
Pearson’s Hard and Soft Acids and Bases (HSAB)
Characterization of the hard bodies
Who you callin’ soft?
Strapping on a Cape: Superacids
Part II: Rules of Attraction: Chemical Bonding
Chapter 6: No Mr. Bond, I Expect You to π: Covalent Bonding
Connecting the Dots: Lewis Structures
Counting electrons
Placing electrons
Price tags in black ties? Formal charges
Returning to the drawing board: Resonance structures
Keeping Your Distance: VSEPR
Ante Up One Electron: Valence-Bond Theory
Summing It All Up: Molecular Orbital Theory
Types of MOs
Evens and odds: Gerade and ungerade symmetry
Identical twins: Homonuclear diatomic molecules
Fraternal twins: Heteronuclear diatomic molecules
Chapter 7: Molecular Symmetry and Group Theory
Identifying Molecules: Symmetry Elements and Operations
Identity
n-fold rotational axis
Inversion center
Mirror planes
Improper rotation axis
It’s Not Polite to Point! Molecular Point Groups
Being Such a Character Table
Dissecting a character table
Degrees of freedom
A glitch in the matrix: Matrix math
Reducible reps
Infrared and Raman active modes
Chapter 8: Ionic and Metallic Bonding
Blame It on Electrostatic Attraction: Forming Ionic Bonds
Marrying a cation and an anion
Measuring bond strength: Lattice energy
Coexisting with covalent bonds
Conducting electricity in solution
Admiring Ionic Crystals
Studying shapes: Lattice types
Size matters (when it’s ionic)
“I’m Melting!” Dissolving Ionic Compounds with Water: Solubility
Just add water: Hydrated ions
Counting soluble compounds
What Is a Metal, Anyway?
Tracing the history of metallurgy
Admiring the properties of solid metals
Delocalizing electrons: Conductivity
Analyzing alloys
Swimming in the Electron Sea: Metallic Bonding Theories
Free-electron theory
Valence bond theory
Band theory
Chapter 9: Clinging to Complex Ions: Coordination Complexes
Counting bonds
Seeking stability
Grouping geometries
Identifying Isomers
Connecting differently: Structural isomers
Arranged differently: Stereoisomers
Naming Coordination Complexes
Sorting Out the Salts
Creating Metal Complexes throughout the Periodic Table
Alkali metals
Alkali earth metals
Transition metals
Lanthanides and actinides
Metalloids
Applying Coordination Complexes in the Real World
Part III: It’s Elemental: Dining at the Periodic Table
Chapter 10: What the H? Hydrogen!
Visiting Hydrogen at Home: Its Place in the Periodic Table
Appreciating the Merits of Hydrogen
Available in abundance
Molecular properties
Nuclear spin
Introducing Hydrogen Isotopes
Investing in Hydrogen Bonds
Forming a hydrogen ion
Creating hydrides
Applying Itself: Hydrogen’s Uses in Chemistry and Industry
Chapter 11: Earning Your Salt: The Alkali and Alkaline Earth Metals
Salting the Earth: Group 1 Elements
Lithium the outlier
Seafaring sodium
Maintaining your brain with potassium
Rubidium, cesium, francium, oh my
Reacting Less Violently: The Group 2 Alkaline Earth Metals
Being beryllium
Magnificent magnesium
Commonly calcium
Strontium, barium, radium
Diagramming the Diagonal Relationship
Chapter 12: The Main Groups
Placing Main Group Elements on the Periodic Table
Lucky 13: The Boron Group
Not-so-boring boron
An abundance of aluminum
Mendeleev’s Missing Link: Gallium
Increasing indium use
Toxic thallium
The Diamond Club: The Carbon Group
Captivating carbon
Coming in second: Silicon
Germane germanium
Malleable tin cans
Plumbing lead
Noting Pnictides of the Nitrogen Group
Leading the pnictides: Nitrogen
Finding phosphorus everywhere
Melding the metalloids: Arsenic and antimony
Keeping Up with the Chalcogens
Oxygen all around
Sulfur
From the Earth to the moon
Marco — polonium!
(Re)Active Singles: The Group 17 Halogens
Cleaning up with chlorine
Briny bromine
Iodine
Rarely astatine
Lights of New York: The Group 18 Noble Gases
Chapter 13: Bridging Two Sides of the Periodic Table: The Transition Metals
Getting to Know Transition Metals
Sorting T-metals into series
Separating T-metals from the main group
Partially Filling d-Orbitals
Calculating an effective nuclear charge
Forming more than one oxidation state
Splitting the Difference: Crystal Field Theory and Transition Metal Complexes
Dividing d-orbitals
Absorbing light waves: Color
Building attraction: Magnetism
Electronic Structure and Bonding
Reacting with other elements
Creating coordination complexes
Adsorbing gas: T-metals in catalysis
Chapter 14: Finding What Lies Beneath: The Lanthanides and Actinides
Spending Quality Time with the Rare Earth Elements: Lanthanides
Electronic structure
Reactivity
Lanthanide contraction
Separating the lanthanide elements
Using lanthanides
Feelin’ Radioactive: The Actinides
Finding or making actinides
Examining electronic structure
Comparing Reactivity: Actinide versus Lanthanide
Looking More Closely at Uranium
Part IV: Special Topics
Chapter 15: Not Quite Organic, Not Quite Inorganic: Organometallics
Building Organometallic Complexes
Adhering to Electron Rules
Counting to eight: The octet rule
Calculating with the 18-electron rule
Settling for 16 electrons
Effectively using the EAN rule
Bonding with Metals: Ligands
Including Carbon: Carbonyls
Providing the Best Examples
e-precise carbon
e-rich nitrogen
e- deficient boron
Behaving Oddly: Organometallics of Groups 1, 2, and 12
Sandwiched Together: Metallocenes
Clustering Together: Metal-Metal Bonding
Creating Vacancies: Insertion and Elimination
Synthesizing Organometallics
Showing Similarities with Main Group Chemistry
Chapter 16: Accelerating Change: Catalysts
Speeding Things Up – The Job of a Catalyst
Considering Types of Catalysts
Homogenous catalysts
Heterogeneous
Organocatalysts
Chapter 17: Bioinorganic Chemistry: Finding Metals in Living Systems
Focusing on Photosynthesis
Climbing Aboard the Oxygen Transport
Feeding a Nitrogen Fixation
Fixing nitrogen for use by organisms
Re-absorbing nitrogen
Being Human
Making things happen: Enzymes
Curing disease: Medicines
Causing problems: Toxicity
Answering When Nature Calls: Environmental Chemistry
Eyeing key indicators
Rocking the heavy metals
Killing me softly: Pesticides
Looking for and removing contaminants
Chapter 18: Living in a Materials World: Solid-State Chemistry
Studying Solid Structures
Building crystals with unit cells
Labeling lines and corners: Miller indices
Three Types of Crystal Structure
Simple crystal structures
Binary crystal structures
Complex crystal structures
Calculating Crystal Formation: The Born-Haber Cycle
Bonding and Other Characteristics
Characterizing size
Dissolving in liquids: Solubility
Encountering zero resistance: Superconductivity
Information technology: Semiconductors
Synthesizing Solid Structures
Detecting Crystal Defects
Chapter 19: Nanotechnology
Defining nanotechnology
History of nanotechnology
The science of nanotechnology
Top-down versus bottom-up
Nanomaterials
Size and shape control
Self-assembly and gray goo
Applications for Nanotechnology
Cancer therapy
Catalysis
Education
Part V: The Part of Tens
Chapter 20: Ten Nobels
Locating Ligands: Alfred Werner
Making Ammonia: Fritz Haber
Creating Transuranium Elements: McMillan and Seaborg
Adding Electronegativity: Pauling
Preparing Plastics: Ziegler and Natta
Sandwiching Compounds: Fischer and Wilkinson
Illuminating Boron Bonds: Lipscomb
Characterizing Crystal Structures: Hauptman and Karle
Creating Cryptands: Jean-Marie Lehn
Making Buckyballs
Chapter 21: Tools of the Trade: Ten Instrumental Techniques
Absorbing and Transmitting Light Waves: UV-vis and IR
Catching Diffracted Light: XRD
Rearranging Excited Atoms: XRF
Measuring Atoms in Solution: ICP/AA
Detecting Secondary Electrons: SEM
Reading the Criss-Crossed Lines: TEM
Characterizing Surface Chemistry: XPS
Evaporating Materials: TGA
Cyclic Voltammetry
Tracking Electron Spin: EPR
Chapter 22: Ten Experiments
Turning Blue: The Clock Reaction
Forming Carbon Dioxide
The Presence of Carbon Dioxide
Mimicking Solubility
Separating Water into Gas
Testing Conductivity of Electrolyte Solutions
Lemon Batteries
Purifying Hydrogen
Colorful Flames
Making Gunpowder
Chapter 23: Ten Inorganic Household Products
Salting Your Food
Bubbling with Hydrogen Peroxide
Baking with Bicarbonate
Whitening with Bleach
Using Ammonia in Many Ways
Killing Pests with Borax
Soothing Babies with Talc
Cleaning with Lye
Scratching Stainless Steel
Wrapping It Up with Aluminum Foil
Glossary
Cheat Sheet

Inorganic Chemistry For Dummies®
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About the Authors
Michael L. Matson started studying chemistry at the U.S. Naval Academy in Annapolis, Maryland. After leaving the Navy, Michael started a PhD program at Rice University, studying the use of carbon nanotubes for medical diagnosis and treatment of cancer. Specifically, Michael focused on internalizing radioactive metal ions within carbon nanotubes: Some radioactive metals could be pictured with special cameras for diagnosis, whereas others were so powerful they could kill cells for treatment. It was at Rice that Michael and Alvin met. Following Rice, Michael went to the University of Houston-Downtown to begin a tenure-track professorship. Happily married to a woman he first met in seventh grade, Michael has two young children, a yellow Labrador retriever named Flounder, is a volunteer firefighter and sommelier, and enjoys CrossFitting.
Alvin W. Orbaek was introduced to chemistry at Rice University (Houston, Texas) by way of nanotechnology, where he studied single-walled carbon nanotubes, transition metal catalysts, and silver nanoparticles. He had previously received a degree in Experimental Physics from N.U.I. Galway (Ireland) and moved into the study of space science and technology at the International Space University (Strasbourg, France). He received a position on Galactic Suite, an orbiting space hotel. To date, he enjoys life by sailing, snowboarding, and DJing. He has been spinning vinyl records since the Atlantic Hotel used to rave, and the sun would set in Ibiza. He hopes to empower people through education and technology, to that effect he is currently completing a PhD in Chemistry at Rice University.
Dedications
Michael: To my wife, Samantha.
Alvin: To Declan, Ann Gitte, Anton, Anna-livia, and Bedstemor.
Authors’ Acknowledgments
Michael: I’d like to acknowledge the immeasurable amounts of assistance from Matt Wagner, Susan Hobbs, Lindsay Lefevere, Alecia Spooner, and Joan Freedman.
Alvin: Without John Wiley & Sons, there would be no book, and for that I am very grateful. Particularly because of the very positive and professional attitude by which they carry out their business; thanks for getting it done. It was a blessing to work with you. In particular, I would like to mention Alecia Spooner, Susan Hobbs (Suz), and Lindsay Lefevere, and thanks to the technical editors (Reynaldo Barreto and Bradley Fahlman) for their crucial input. I would also like to thank Matt Wagner for invaluable support and assistance. And to Mike Matson, thank you for the invitation to write this book.
I have had many teachers, mentors, and advisors throughout the years, but there are five who deserve attention. Andrew Smith at Coleenbridge Steiner school, where I enjoyed learning a great deal. John Treacy, who made every science class the most riveting class each day. Pat Sweeney, whose habit of teaching would leave anyone engrossed in mathematics. To Ignasi Casanova for his mentorship and introduction to the nanos. And Andrew Barron, both my PhD advisor and mentor, to whom I owe a great deal of credit, due in no small part to his measure of tutelage.
But all this stands upon a firm foundation that is based on the support of Dec, Gitte, Anton, and Anna; here’s to next Christmas — whenever. There are many other friends and family who have contributed to this work, too many to mention them all. But I’d especially like to thank my colleagues from the Irish house, who so graciously agreed to read through the text, namely Alan Taylor, Nigel Alley, and Stuart Corr. Also to Sophia Phounsavath and Brandon Cisneros for proofreading. Jorge Fallas for the Schrödinger equation. To Gordon Tomas for continued support of my writing. And to Gabrielle Novello, who fed me wholesome foods while I otherwise converted coffee and sleepless nights into this book. And to Valhalla for those nights when work was not working for me. And to PHlert, the best sailing program on this planet, or any other.
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Introduction
Inorganic chemistry deals with all the atoms on the periodic table, the various rules that govern how they look, and how they interact. At first glance, trying to understand the differences among 112 atoms might seem like a mammoth task. But because of the periodic table, we can bunch them up into groups and periods and make them much easier to grasp.
So welcome to Inorganic Chemistry For Dummies. We hope that through this book you come to learn a great deal about the environment around you, what materials you use on a regular basis, and why some materials are more important to us than others. This book is fun and informative, while at the same time insightful and descriptive. And it’s designed to make this fascinating and practical science accessible to anyone, from the novice chemist to the mad scientist.
About This Book
This book was written in such a way that you can start in any chapter you choose, in the chapter that interests you the most, without having to read all the chapters before it. But the chapters build on material from one chapter to the next, so if you feel more background would help you, feel free to start with Chapter 1. You can also make use of the numerous cross references in each chapter to find pertinent information. But it can also be read like a study guide to help a student understand some of the more complicated aspect of this fascinating science.
We tried to make the information as accessible as possible. Each chapter is broken down into bite-sized chunks that make it easy for you to quickly digest and understand the material presented. Some of the chunks are further broken down into subsections when there’s special need to elaborate further on the concepts being discussed.
Science is a process that requires lots of imagination. It requires more imagination than memory, especially as you start to learn more and more about a certain topic. To help with your imagination we have tried to include helpful graphics and artwork that complement the writing within the text. Further to this we include many real-world examples and interesting historical or scientific tidbits to keep your curiosity piqued.
Conventions Used in This Book
Science progressed more rapidly in the last 200 years than it had in the few thousand years previous. A great deal of this success came from the agreement among scientist to create and use a set of standard conventions. The two most important conventions are the periodic table and the international system of units, called SI units. SI units are based on the metric system, and it’s more common to see temperature expressed as Celsius than Fahrenheit. And you see lengths expressed in meters instead of inches and feet. Weights and mass are expressed in terms of grams instead of pounds or stone.
And the following conventions throughout this text make everything consistent and easy to understand:
All Web addresses appear in monofont
.
New and key terms appear in italics and are closely followed by an easy-to-understand definition.
Bold text highlights the action part of numbered steps.
What You Don’t Need to Read
Sidebars are highlighted in gray-shaded boxes so they’re easy to pick out. They contain fun facts and curious asides, but none of their information is crucial to your understanding of inorganic chemistry. Feel free to just skip over them if you prefer.
Foolish Assumptions
As authors of Inorganic Chemistry For Dummies we may have made a few foolish assumptions about the readership. We assume that you have very little background in chemistry, and possibly none at all; that you’re new to inorganic chemistry, and maybe you have never heard of the subject before. We assume that you know what chemistry is, but not much more than that. This book begins with all the general chemistry info that you need to grasp the concepts and material in the rest of the book. If you have some understanding of general chemistry, however, all the better.
You may be a medical student who needs to brush up in inorganic chemistry, or a high school student getting ready for a science fair, or even a freshman or junior at college. We’ve tailored this book to meet all your needs, and we sincerely hope you find great explanations about the concepts presented that are also engaging, interesting, and useful.
When you finish reading this book and your interest in chemistry is heightened, we recommend that you go to a local bookseller (second-hand book stores are a personal favorite) and find more books that offer other perspectives on inorganic chemistry. There are also excellent resources on the Internet, and many schools make class notes available online. But the best way to get involved in chemistry is by doing it. Chemistry is a fun and exciting field, made evident when you conduct chemistry experiments. Keep an eye out for demonstration kits that enable you to do your own experiments at home. And note that the last chapter of this book offers ten really cool experiments, too.
How This Book Is Organized
This book is organized into multiple parts that group topics together in the most logical way possible. Here’s a brief description of each section of Inorganic Chemistry For Dummies:
Part I: Reviewing Some General Chemistry
Here you are introduced to science in general, and we give you the basic tenets of general chemistry that help you throughout the rest of the book.
In Chapter 1, you start with an introduction to inorganic chemistry, what it is, and why it is important. You learn how it’s different from organic chemistry and how this difference is important for technology and society.
The following chapters of this section deal with topics that are covered in many general chemistry textbooks, but these chapters cover the topics in greater detail than a general chemistry textbook. In Chapter 2 we explain what the atom looks like, how it’s structured, and why this is important for inorganic chemistry. In particular, this chapter delves into the periodic table and how the structure of the atom is described. Chapter 3 introduces oxidation and reduction chemistry that helps you understand why many chemical reactions take place. It deals with the electrons that each atom has and how the electrons can be shuttled around from atom to atom. Then in Chapter 4 we focus on the nucleus and how changes to the nucleus lead to nuclear chemistry. And finally we end this section by talking about acid-base chemistry because this can help you understand the many ways in which atoms and molecules interact with one another.
Part II: Rules of Attraction: Chemical Bonding
In this section we talk about the various ways that atoms can bond with one another. In Chapter 6 we introduce covalent bonding. Chapter 7 deals with molecular symmetry, not just for inorganic chemistry but also fundamental to many of the physical sciences. Ionic and metallic bonding are detailed in Chapter 8.
Chapter 9, like all of the chapters, can be read as a standalone chapter, but it’s much easier to understand if you read through the three preceding chapters. If you get stuck on coordination complexes, however, refer back to the previous three chapters for a little background information.
Part III: It’s Elemental: Dining at the Periodic Table
The periodic table contains over 100 separate and unique elements, which are described in Part III. We cover all the important elements; and to make it easier to digest, we’ve broken them down into five related chapters. Each chapters deals with elements that are similar to each other, making them easier to understand.
To get the ball rolling we introduce hydrogen in Chapter 10, because it’s the most abundant element in the universe and can be found in many chemicals and materials. We then move from left to right on the periodic table, starting off with the alkali and alkali earth elements in Chapter 11. We guide you through the periodic table to the main group elements in Chapter 12, the transition metals in Chapter 13, and finally round out Part III with the lanthanides and actinides in Chapter 14.
Part IV: Special Topics
These chapters cover what makes the study of inorganic chemistry so interesting and also distinguishes it from organic chemistry. However, you will find a great deal of overlap with other fields of study such as material science, physics, and biology.
Inorganic chemistry became a modern science with the advent of organometallic chemistry, described in Chapter 15. Chapter 16 shows you how practical and important catalysis is to the modern world in which we live. Chapter 17 deals with the inorganic chemistry of living systems and the environment. The subject matter makes this chapter unique from the others in this section. This is also true for Chapter 18 where we describe solid state chemistry, the basis of the information technology revolution. Chapter 19 gives you a quick introduction to one of the most interesting and promising technological developments of the modern age, namely nanotechnology.
Part V: The Part of Tens
To make this book even easier to grasp and read, we compiled three important lists to help you in your study of inorganic chemistry. In Chapter 20, we introduce and explain ten common household products. Then, in Chapter 21, you meet ten of the most important Nobel Prizes that were awarded to chemists. Chapter 22 introduces ten instruments and techniques that are commonly found and used in laboratories across the globe. And finally we give you ten experiments that you can try out at home in Chapter 23. Remember, one of the most fun parts of chemistry is doing chemistry, and this chapter gives you some fun experiments to try.
Icons Used in This Book
Throughout this book icons are used to draw your attention to certain information.
This is not often used here, but the Tip icon indicates that some information may be especially useful to you.
When you see the Remember icon you should understand that this information is quite important to understanding the concepts being explained. If you are studying inorganic chemistry, this is one of the most important icons to look for. It can indicate a definition, or be a concise explanation of a concept; at other times it indicates information to help you grasp how various concepts overlap.
The Warning icon tells you to pay close attention to what’s being said because it indicates where a potentially dangerous situation may arise.
The Technical Stuff icon is used to indicate detailed information; for some people, it might not be necessary to read or understand.
Where to Go from Here
You might be taking an inorganic chemistry course, or maybe you’re just curious about the world around you. Regardless, if you’re looking for something specific, you can find it by checking the index or maybe even the glossary. When you know where to find what you are looking for, go right ahead and jump in. And enjoy.